成果報告

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学術論文

[1]  Y. Orikasa, Y. Gogyo, H. Yamashige, M. Katayama, K.Z. Chen, T. Mori, K. Yamamoto, T. Masese, Y. Inada, T. Ohta, Z. Siroma, S. Kato, H. Kinoshita, H. Arai, Z. Ogumi, Y. Uchimoto,
“Ionic Conduction in Lithium Ion Battery Composite Electrode Governs Cross-sectional Reaction Distribution”, Sci. Rep., 6, 26382 (2016).

[2]  T. Mori, T. Masese, Y. Orikasa, Z.D. Huang, T. Okado, J. Kim, Y. Uchimoto,
“Anti-site mixing governs the electrochemical performances of olivine-type MgMnSiO4 cathodes for rechargeable magnesium batteries”, Phys. Chem. Chem. Phys., 18, 13524-13529 (2016).

[3]  X.M. Wang, Y. Orikasa, Y. Uchimoto,
“Platinum-Based Electrocatalysts for the Oxygen-Reduction Reaction: Determining the Role of Pure Electronic Charge Transfer in Electrocatalysis”, ACS Catalysis, 6, 4195-4198 (2016).

[4]  H. Tanida, H. Yamashige, Y. Orikasa, Y. Gogyo, H. Arai, Y. Uchimoto, Z. Ogumi,
“Elucidating the Driving Force of Relaxation of Reaction Distribution in LiCoO2 and LiFePO4 Electrodes Using X-ray Absorption Spectroscopy”, J. Phys. Chem. C, 120, 4739-4743 (2016).

[5]  T. Mori, Y. Orikasa, K. Nakanishi, C. Kezheng, M. Hattori, T. Ohta, Y. Uchimoto,
“Discharge/charge reaction mechanisms of FeS2 cathode material for aluminum rechargeable batteries at 55°C”, J. Power Sources, 313, 9-14 (2016).

[6]  I. Takahashi, T. Mori, T. Yoshinari, Y. Orikasa, Y. Koyama, H. Murayama, K. Fukuda, M. Hatano, H. Arai, Y. Uchimoto, T. Terai,
“Irreversible phase transition between LiFePO4 and FePO4 during high-rate charge-discharge reaction by operando X-ray diffraction”, J. Power Sources, 309, 122-126 (2016).

[7]  K. Ohara, A. Mitsui, M. Mori, Y. Onodera, S. Shiotani, Y. Koyama, Y. Orikasa, M. Murakami, K. Shimoda, K. Mori, T. Fukunaga, H. Arai, Y. Uchimoto, Z. Ogumi,
“Structural and electronic features of binary Li2S-P2S5 glasses”, Sci. Rep., 6, 21302 (2016).

[8]  A. Yamazaki, Y. Orikasa, K. Chen, Y. Uchimoto, T. Kamiya, M. Koka, T. Satoh, K. Mima, Y. Kato, K. Fujita,
“In-situ measurement of the lithium distribution in Li-ion batteries using micro-IBA techniques”, Nucl. Instrum. Meth. B, 371, 298-302 (2016).

[9]  K. Suzuki, B. Barbiellini, Y. Orikasa, S. Kaprzyk, M. Itou, K. Yamamoto, Y.J. Wang, H. Hafiz, Y. Uchimoto, A. Bansil, Y. Sakurai, H. Sakurai,
“Non-destructive measurement of in-operando lithium concentration in batteries via x-ray Compton scattering”, J. Appl. Phys., 119, 025103 (2016).

[10]  T. Matsuyama, M. Deguchi, K. Mitsuhara, T. Ohta, T. Mori, Y. Orikasa, Y. Uchimoto, Y. Kowada, A. Hayashi, M. Tatsumisago,
“Structure analyses using X-ray photoelectron spectroscopy and X-ray absorption near edge structure for amorphous MS3 (M: Ti, Mo) electrodes in all-solid-state lithium batteries”, J. Power Sources, 313, 104-111 (2016).

[11]  J. Maruyama, T. Hasegawa, S. Iwasaki, T. Fukuhara, Y. Orikasa, Y. Uchimoto,
“Carbonaceous thin film coating with Fe-N-4 site for enhancement of dioxovanadium ion reduction”, J. Power Sources, 324, 521-527 (2016).

[12]  D. Kan, Y. Orikasa, K. Nitta, H. Tanida, R. Kurosaki, T. Nishimura, T. Sasaki, H.C. Guo, Y. Ozaki, Y. Uchimoto, Y. Shimakawa,
“Overpotential-Induced Introduction of Oxygen Vacancy in La0.67Sr0.33MnO3 Surface and Its Impact on Oxygen Reduction Reaction Catalytic Activity in Alkaline Solution”, J. Phys. Chem. C, 120, 6006-6010 (2016).

[13]  D. Takamatsu, Y. Orikasa, S. Mori, T. Nakatsutsumi, K. Yamamoto, Y. Koyama, T. Minato, T. Hirano, H. Tanida, H. Arai, Y. Uchimoto, Z. Ogumi,
“Effect of an Electrolyte Additive of Vinylene Carbonate on the Electronic Structure at the Surface of a Lithium Cobalt Oxide Electrode under Battery Operating Conditions”, J. Phys. Chem. C, 119, 9791-9797 (2015).

[14]  K. Suzuki, B. Barbiellini, Y. Orikasa, N. Go, H. Sakurai, S. Kaprzyk, M. Itou, K. Yamamoto, Y. Uchimoto, Y.J. Wang, H. Hafiz, A. Bansil, Y. Sakurai,
“Extracting the Redox Orbitals in Li Battery Materials with High-Resolution X-Ray Compton Scattering Spectroscopy”, Phys. Rev. Lett., 114, 087401 (2015).

[15]  Y. Orikasa,
“Hierarchical Spatiotemporal Analyses of Reactions Using Synchrotron Radiation and the Design of Next-Generation Energy Conversion Devices”, Electrochemistry, 83, 695-700 (2015).

[16]  M. Oishi, C. Yogi, I. Watanabe, T. Ohta, Y. Orikasa, Y. Uchimoto, Z. Ogumi,
“Direct observation of reversible charge compensation by oxygen ion in Li-rich manganese layered oxide positive electrode material, Li1.16Ni0.15Co0.19Mn0.50O2”, J. Power Sources, 276, 89-94 (2015).

[17]  K. Ohara, Y. Umebayashi, T. Ichitsubo, K. Matsumoto, R. Hagiwara, H. Arai, M. Mori, Y. Orikasa, S. Okamoto, M. Oishi, Y. Aiso, T. Nohira, Y. Uchimoto, Z. Ogumi, E. Matsubara,
“Structural modification by adding Li cations into Mg/Cs-TFSA molten salt facilitating Mg electrodeposition”, RSC Adv., 5, 3063-3069 (2015).

[18]  T. Masese, C. Tassel, Y. Orikasa, Y. Koyama, H. Arai, N. Hayashi, J. Kim, T. Mori, K. Yamamoto, Y. Kobayashi, H. Kageyama, Z. Ogumi, Y. Uchimoto,
“Crystal Structural Changes and Charge Compensation Mechanism during Two Lithium Extraction/Insertion between Li2FeSiO4 and FeSiO4”, J. Phys. Chem. C, 119, 10206-10211 (2015).

[19]  J. Maruyama, T. Hasegawa, S. Iwasaki, T. Fukuhara, Y. Orikasa, Y. Uchimoto,
“Catalysis of Vanadium Ion Redox Reactions on Carbonaceous Material with Metal-N-4 Sites”, Chemcatchem, 7, 2305-2308 (2015).

[20]  H. Komatsu, H. Arai, Y. Koyama, K. Sato, T. Kato, R. Yoshida, H. Murayama, I. Takahashi, Y. Orikasa, K. Fukuda, T. Hirayama, Y. Ikuhara, Y. Ukyo, Y. Uchimoto, Z. Ogumi,
“Solid Solution Domains at Phase Transition Front of LixNi0.5Mn1.5O4”, Adv. Energy Mater., 5, 1500638 (2015).

[21]  M. Itou, Y. Orikasa, Y. Gogyo, K. Suzuki, H. Sakurai, Y. Uchimoto, Y. Sakurai,
“Compton scattering imaging of a working battery using synchrotron high-energy X-rays”, J. Synchrotron Rad., 22, 161-164 (2015).

[22]  Z.D. Huang, T. Masese, Y. Orikasa, T. Mori, K. Yamamoto,
“Vanadium phosphate as a promising high-voltage magnesium ion (de)-intercalation cathode host”, RSC Adv., 5, 8598-8603 (2015).

[23]  R. Gonzalez-Arrabal, M. Panizo-Laiz, K. Fujita, K. Mima, A. Yamazaki, T. Kamiya, Y. Orikasa, Y. Uchimoto, H. Sawada, C. Okuda, Y. Kato, J.M. Perlado,
“Meso-scale characterization of lithium distribution in lithium-ion batteries using ion beam analysis techniques”, J. Power Sources, 299, 587-595 (2015).

[24]  D. Yonekura, E. Iwama, N. Ota, M. Muramatsu, M. Saito, Y. Orikasa, W. Naoi, K. Naoi,
“Progress of the conversion reaction of Mn3O4 particles as a function of the depth of discharge”, Phys. Chem. Chem. Phys., 16, 6027-6032 (2014).

[25]  K. Yamamoto, Y. Orikasa, D. Takamatsu, Y. Koyama, S. Mori, T. Masese, T. Mori, T. Minato, H. Tanida, T. Uruga, Z. Ogumi, Y. Uchimoto,
“Stabilization of the Electronic Structure at the Cathode/Electrolyte Interface via MgO Ultra-thin Layer during Lithium-ions Insertion/Extraction”, Electrochemistry, 82, 891-896 (2014).
[26]  K. Yamamoto, T. Minato, S. Mori, D. Takamatsu, Y. Orikasa, H. Tanida, K. Nakanishi, H. Murayama, T. Masese, T. Mori, H. Arai, Y. Koyama, Z. Ogumi, Y. Uchimoto,
“Improved Cyclic Performance of Lithium-Ion Batteries: An Investigation of Cathode/Electrolyte Interface via In Situ Total-Reflection Fluorescence X-ray Absorption Spectroscopy”, J. Phys. Chem. C, 118, 9538-9543 (2014).

[27]  H. Tanida, K. Fukuda, H. Murayama, Y. Orikasa, H. Arai, Y. Uchimoto, E. Matsubara, T. Uruga, K. Takeshita, S. Takahashi, M. Sano, H. Aoyagi, A. Watanabe, N. Nariyama, H. Ohashi, H. Yumoto, T. Koyama, Y. Senba, T. Takeuchi, Y. Furukawa, T. Ohata, T. Matsushita, Y. Ishizawa, T. Kudo, H. Kimura, H. Yamazaki, T. Tanaka, T. Bizen, T. Seike, S. Goto, H. Ohno, M. Takata, H. Kitamura, T. Ishikawa, T. Ohta, Z. Ogumi,
“RISING beamline (BL28XU) for rechargeable battery analysis”, J. Synchrotron Rad., 21, 268-272 (2014).

[28]  D. Takamatsu, Y. Koyama, Y. Orikasa, S. Mori, T. Nakatsutsumi, T. Hirano, H. Tanida, H. Arai, Y. Uchimoto, Z. Ogumi,
“Electrochemical and Spectroscopic Characterization of LiCoO2 Thin-Film as Model Electrode”, J. Electrochem. Soc., 161, A1447-A1452 (2014).

[29]  Y. Orikasa, D. Takamatsu, K. Yamamoto, Y. Koyama, S. Mori, T. Masese, T. Mori, T. Minato, H. Tanida, T. Uruga, Z. Ogumi, Y. Uchimoto,
“Origin of Surface Coating Effect for MgO on LiCoO2 to Improve the Interfacial Reaction between Electrode and Electrolyte”, Adv. Mater. Interfaces, 1, 1400195 (2014).

[30]  Y. Orikasa, T. Masese, Y. Koyama, T. Mori, M. Hattori, K. Yamamoto, T. Okado, Z.D. Huang, T. Minato, C. Tassel, J. Kim, Y. Kobayashi, T. Abe, H. Kageyama, Y. Uchimoto,
“High energy density rechargeable magnesium battery using earth-abundant and non-toxic elements”, Sci. Rep., 4, 5622 (2014).

[31]  Y. Orikasa, T. Ina, K. Yamamoto, T. Nakao, A. Mineshige, K. Amezawa, T. Kawada, H. Tanida, T. Uruga, Y. Uchimoto,
“Direct Observation of Rate Determining Step for Nd2NiO4+delta SOFC Cathode Reaction by operando Electrochemical XAS”, Electrochemistry, 82, 897-900 (2014).

[32]  Y. Orikasa, E.J. Crumlin, S. Sako, K. Amezawa, T. Uruga, M.D. Biegalski, H.M. Christen, Y. Uchimoto, Y. Shao-Horn,
“Surface Strontium Segregation of Solid Oxide Fuel Cell Cathodes Proved by In Situ Depth-Resolved X-ray Absorption Spectroscopy”, ECS Electrochem. Lett., 3, F23-F26 (2014).

[33]  K. Nakanishi, D. Kato, H. Arai, H. Tanida, T. Mori, Y. Orikasa, Y. Uchimoto, T. Ohta, Z. Ogumi,
“Novel spectro-electrochemical cell for in situ/operando observation of common composite electrode with liquid electrolyte by X-ray absorption spectroscopy in the tender X-ray region”, Rev. Sci. Instrum., 85, 084103 (2014).

[34]  T. Masese, Y. Orikasa, C. Tassel, J. Kim, T. Minato, H. Arai, T. Mori, K. Yamamoto, Y. Kobayashi, H. Kageyama, Z. Ogumi, Y. Uchimoto,
“Relationship between Phase Transition Involving Cationic Exchange and Charge-Discharge Rate in Li2FeSiO4”, Chem. Mater., 26, 1380-1384 (2014).

[35]  T. Masese, Y. Orikasa, T. Mori, K. Yamamoto, T. Ina, T. Minato, K. Nakanishi, T. Ohta, C. Tassel, Y. Kobayashi, H. Kageyama, H. Arai, Z. Ogumi, Y. Uchimoto,
“Local structural change in Li2FeSiO4 polyanion cathode material during initial cycling”, Solid State Ionics, 262, 110-114 (2014).

[36]  J. Maruyama, T. Ioroi, T. Hasegawa, T. Mori, Y. Orikasa, Y. Uchimoto,
“Carbonaceous Hydrogen-Evolution Catalyst Containing Cobalt Surrounded by a Tuned Local Structure”, Chemcatchem, 6, 2197-2200 (2014).

[37]  K. Kisu, M. Iijima, E. Iwama, M. Saito, Y. Orikasa, W. Naoi, K. Naoi,
“The origin of anomalous large reversible capacity for SnO2 conversion reaction”, J. Mater. Chem. A, 2, 13058-13068 (2014).

[38]  H. Kawaura, D. Takamatsu, S. Mori, Y. Orikasa, H. Sugaya, H. Murayama, K. Nakanishi, H. Tanida, Y. Koyama, H. Arai, Y. Uchimoto, Z. Ogumi,
“High potential durability of LiNi0.5Mn1.5O4 electrodes studied by surface sensitive X-ray absorption spectroscopy”, J. Power Sources, 245, 816-821 (2014).

[39]  T. Ina, Y. Orikasa, T. Masese, T. Nakao, A. Mineshige, K. Amezawa, H. Tanida, T. Uruga, Y. Uchimoto,
“Relationship between Local Structure and Oxide Ionic Diffusion of Nd2NiO4+delta with K2NiF4 Structure”, Electrochemistry, 82, 875-879 (2014).

[40]  Z.D. Huang, T. Masese, Y. Orikasa, T. Mori, T. Minato, C. Tassel, Y. Kobayashi, H. Kageyama, Y. Uchimoto,
“MgFePO4F as a feasible cathode material for magnesium batteries”, J. Mater. Chem. A, 2, 11578-11582 (2014).

[41]  C.-Y. Chen, K. Matsumoto, T. Nohira, R. Hagiwara, Y. Orikasa, Y. Uchimoto,
“Pyrophosphate Na2FeP2O7 as a low-cost and high-performance positive electrode material for sodium secondary batteries utilizing an inorganic ionic liquid”, J. Power Sources, 246, 783-787 (2014).

[42]  X.M. Wang, Y. Orikasa, Y. Takesue, H. Inoue, M. Nakamura, T. Minato, N. Hoshi, Y. Uchimoto,
“Quantitating the Lattice Strain Dependence of Monolayer Pt Shell Activity toward Oxygen Reduction”, J. Am. Chem. Soc., 135, 5938-5941 (2013).

[43]  H. Tanida, H. Yamashige, Y. Orikasa, T. Fujimoto, M. Oishi, H. Murayama, H. Arai, M. Katayama, Y. Inada, T. Ohta, Y. Uchimoto, Z. Ogumi,
“In situ two-dimensional micro-imaging XAFS with CCD detector”, J Phys Conf Ser, 430, 012021 (2013).

[44]  T. Takeguchi, T. Yamanaka, H. Takahashi, H. Watanabe, T. Kuroki, H. Nakanishi, Y. Orikasa, Y. Uchimoto, H. Takano, N. Ohguri, M. Matsuda, T. Murota, K. Uosaki, W. Ueda,
“Layered Perovskite Oxide: A Reversible Air Electrode for Oxygen Evolution/Reduction in Rechargeable Metal-Air Batteries”, J. Am. Chem. Soc., 135, 11125-11130 (2013).

[45]  D. Takamatsu, S. Mori, Y. Orikasa, T. Nakatsutsumi, Y. Koyama, H. Tanida, H. Arai, Y. Uchimoto, Z. Ogumi,
“Effects of ZrO2 Coating on LiCoO2 Thin-Film Electrode Studied by In Situ X-ray Absorption Spectroscopy”, J. Electrochem. Soc., 160, A3054-A3060 (2013).

[46]  Y. Orikasa, T. Maeda, Y. Koyama, H. Murayama, K. Fukuda, H. Tanida, H. Arai, E. Matsubara, Y. Uchimoto, Z. Ogumi,
“Transient Phase Change in Two Phase Reaction between LiFePO4 and FePO4 under Battery Operation”, Chem. Mater., 25, 1032-1039 (2013).

[47]  Y. Orikasa, T. Maeda, Y. Koyama, H. Murayama, K. Fukuda, H. Tanida, H. Arai, E. Matsubara, Y. Uchimoto, Z. Ogumi,
“Direct Observation of a Metastable Crystal Phase of LixFePO4 under Electrochemical Phase Transition”, J. Am. Chem. Soc., 135, 5497-5500 (2013).

[48]  Y. Orikasa, T. Maeda, Y. Koyama, T. Minato, H. Murayama, K. Fukuda, H. Tanida, H. Arai, E. Matsubara, Y. Uchimoto, Z. Ogumi,
“Phase Transition Analysis between LiFePO4 and FePO4 by In-Situ Time-Resolved X-ray Absorption and X-ray Diffraction”, J. Electrochem. Soc., 160, A3061-A3065 (2013).

[49]  M. Oishi, T. Fujimoto, Y. Takanashi, Y. Orikasa, A. Kawamura, T. Ina, H. Yamashige, D. Takamatsu, K. Sato, H. Murayama, H. Tanida, H. Arai, H. Ishii, C. Yogi, I. Watanabe, T. Ohta, A. Mineshige, Y. Uchimoto, Z. Ogumi,
“Charge compensation mechanisms in Li1.16Ni0.15Co0.19Mn0.50O2 positive electrode material for Li-ion batteries analyzed by a combination of hard and soft X-ray absorption near edge structure”, J. Power Sources, 222, 45-51 (2013).

[50]  Z.D. Huang, Y. Orikasa, T. Masese, K. Yamamoto, T. Mori, T. Minato, Y. Uchimoto,
“A novel cationic-ordering fluoro-polyanionic cathode LiV0.5Fe0.5PO4F and its single phase Li+ insertion/extraction behaviour”, RSC Adv., 3, 22935-22939 (2013).

[51]  H. Arai, K. Sato, Y. Orikasa, H. Murayama, I. Takahashi, Y. Koyama, Y. Uchimoto, Z. Ogumi,
“Phase transition kinetics of LiNi0.5Mn1.5O4 electrodes studied by in situ X-ray absorption near-edge structure and X-ray diffraction analysis”, J. Mater. Chem. A, 1, 10442-10449 (2013).

[52]  D. Takamatsu, Y. Koyama, Y. Orikasa, S. Mori, T. Nakatsutsumi, T. Hirano, H. Tanida, H. Arai, Y. Uchimoto, Z. Ogumi,
“First In Situ Observation of the LiCoO2 Electrode/Electrolyte Interface by Total-Reflection X-ray Absorption Spectroscopy”, Angew. Chem. Int. Ed., 51, 11597-11601 (2012).

[53]  H. Tanida, H. Yamashige, Y. Orikasa, M. Oishi, Y. Takanashi, T. Fujimoto, K. Sato, D. Takamatsu, H. Murayama, H. Arai, E. Matsubara, Y. Uchimoto, Z. Ogumi,
“In situ two-dimensional imaging quick-scanning XAFS with pixel array detector”, J. Synchrotron Rad., 18, 919-922 (2011).

[54]  Y. Takanashi, Y. Orikasa, M. Mogi, M. Oishi, H. Murayama, K. Sato, H. Yamashige, D. Takamatsu, T. Fujimoto, H. Tanida, H. Arai, T. Ohta, E. Matsubara, Y. Uchimoto, Z. Ogumi,
“Thickness estimation of interface films formed on Li1-xCoO2 electrodes by hard X-ray photoelectron spectroscopy”, J. Power Sources, 196, 10679-10685 (2011).

[55]  D. Takamatsu, T. Nakatsutsumi, S. Mori, Y. Orikasa, M. Mogi, H. Yamashige, K. Sato, T. Fujimoto, Y. Takanashi, H. Murayama, M. Oishi, H. Tanida, T. Uruga, H. Arai, Y. Uchimoto, Z. Ogumi,
“Nanoscale Observation of the Electronic and Local Structures of LiCoO2 Thin Film Electrode by Depth-Resolved X-ray Absorption Spectroscopy”, J. Phys. Chem. Lett., 2, 2511-2514 (2011).

[56]  Y. Orikasa, T. Nakao, M. Oishi, T. Ina, A. Mineshige, K. Amezawa, H. Arai, Z. Ogumi, Y. Uchimoto,
“Local structural analysis for oxide ion transport in La0.6Sr0.4FeO3-delta cathodes”, J. Mater. Chem., 21, 14013-14019 (2011).

[57]  Y. Orikasa, T. Ina, T. Nakao, A. Mineshige, K. Amezawa, M. Oishi, H. Arai, Z. Ogumi, Y. Uchimoto,
“An X-ray absorption spectroscopic study on mixed conductive La0.6Sr0.4Co0.8Fe0.2O3-delta cathodes. I. Electrical conductivity and electronic structure”, Phys. Chem. Chem. Phys., 13, 16637-16643 (2011).

[58]  Y. Orikasa, T. Ina, T. Nakao, A. Mineshige, K. Amezawa, M. Oishi, H. Arai, Z. Ogumi, Y. Uchimoto,
“X-ray Absorption Spectroscopic Study on La0.6Sr0.4CoO3-delta Cathode Materials Related with Oxygen Vacancy Formation”, J. Phys. Chem. C, 115, 16433-16438 (2011).

[59]  T. Okumura, T. Nakatsutsumi, T. Ina, Y. Orikasa, H. Arai, T. Fukutsuka, Y. Iriyama, T. Uruga, H. Tanida, Y. Uchimoto, Z. Ogumi,
“Depth-resolved X-ray absorption spectroscopic study on nanoscale observation of the electrode-solid electrolyte interface for all solid state lithium ion batteries”, J. Mater. Chem., 21, 10051-10060 (2011).

[60]  T. Okumura, T. Ina, Y. Orikasa, H. Arai, Y. Uchimoto, Z. Ogumi,
“Effect of average and local structures on lithium ion conductivity in La2/3-xLi3xTiO3”, J. Mater. Chem., 21, 10195-10205 (2011).

[61]  T. Okumura, T. Ina, Y. Orikasa, H. Arai, Y. Uchimoto, Z. Ogumi,
“Improvement of lithium ion conductivity for A-site disordered lithium lanthanum titanate perovskite oxides by fluoride ion substitution”, J. Mater. Chem., 21, 10061-10068 (2011).

[62]  T. Okumura, T. Fukutsuka, A. Yanagihara, Y. Orikasa, H. Arai, Z. Ogumi, Y. Uchimoto,
“Electronic and local structural changes with lithium-ion insertion in TiO2-B: X-ray absorption spectroscopy study”, J. Mater. Chem., 21, 15369-15377 (2011).

[63]  T. Okumura, T. Fukutsuka, A. Yanagihara, Y. Orikasa, H. Arai, Z. Ogumi, Y. Uchimoto,
“Nanosized Effect on Electronic/Local Structures and Specific Lithium-Ion Insertion Property in TiO2-B Nanowires Analyzed by X-ray Absorption Spectroscopy”, Chem. Mater., 23, 3636-3644 (2011).

[64]  T. Okumura, T. Fukutsuka, K. Matsumoto, Y. Orikasa, H. Arai, Z. Ogumi, Y. Uchimoto,
“Role of Local and Electronic Structural Changes with Partially Anion substitution Lithium Manganese Spinel Oxides on Their Electrochemical Properties: X-ray Absorption Spectroscopy Study”, Dalton T, 40, 9752-9764 (2011).

[65]  T. Okumura, T. Fukutsuka, K. Matsumoto, Y. Orikasa, H. Arai, Z. Ogumi, Y. Uchimoto,
“Lithium-Ion Transfer Reaction at the Interface between Partially Fluorinated Insertion Electrodes and Electrolyte Solutions”, J. Phys. Chem. C, 115, 12990-12994 (2011).

[66]  J. Maruyama, T. Hasegawa, T. Amano, Y. Muramatsu, E.M. Gullikson, Y. Orikasa, Y. Uchimoto,
“Pore Development in Carbonized Hemoglobin by Concurrently Generated MgO Template for Activity Enhancement as Fuel Cell Cathode Catalyst”, ACS Appl. Mater. Interfaces, 3, 4837-4843 (2011).

[67]  G.J. la O’, S.J. Ahn, E. Crumlin, Y. Orikasa, M.D. Biegalski, H.M. Christen, Y. Shao-Horn,
“Catalytic Activity Enhancement for Oxygen Reduction on Epitaxial Perovskite Thin Films for Solid-Oxide Fuel Cells”, Angew. Chem. Int. Ed., 49, 5344-5347 (2010).

[68]  K. Amezawa, T. Ina, Y. Orikasa, A. Unemoto, H. Watanabe, F. Iguchi, Y. Terada, T. Fukutsuka, T. Kawada, H. Yugami, Y. Uchimoto,
“Investigation on Oxygen Potential Distribution in a ZrO2-Based Solid Electrolyte by Using In-Situ Micro XAS Technique”, ECS Transactions, 25, 345-348 (2009).

[69]  Y. Orikasa, T. Ina, T. Fukutsuka, K. Amezawa, T. Kawada, Y. Uchimoto,
“X-Ray Absorption Spectroscopic Studies on Electronic Structure in La0.6Sr0.4Co0.8Fe0.2O3-δ Perovskite-Type Oxides”, ECS Transactions, 13, 201-205 (2008).

[70]  T. Ina, Y. Orikasa, T. Fukutsuka, K. Amezawa, T. Kawada, Y. Uchimoto,
“Studies on Defect Structures of (La,Sr)2NiO4 by Using X-ray Absorption Spectroscopy”, ECS Transactions, 13, 195-200 (2008).

[71]  K. Amezawa, Y. Orikasa, T. Ina, A. Unemoto, M. Sase, H. Watanabe, T. Fukutsuka, T. Kawada, Y. Terada, Y. Uchimoto,
“Electronic and Local Structures of La1-x SrxCoO3-δ Studied by In-Situ Micro XAS Measurements”, ECS Transactions, 13, 161-164 (2008).

[72]  Y. Orikasa, N. Hayashi, S. Muranaka,
“Effects of oxygen gas pressure on structural, electrical, and thermoelectric properties of (ZnO)(3)In(2)O(3) thin films deposited by rf magnetron sputtering”, J. Appl. Phys., 103, 113703 (2007).

[73]  Y. Orikasa, N. Hayashi, S. Muranaka,
“Preparation and Electrical Properties of Zn3In2O6 Thin Films”, J. Jpn. Soc. Powder Powder Metallurgy, 54, 121-125 (2007).

解説・総説

1.折笠 有基, 「硬X線分光を用いたリチウムイオン電池のOperando解析」,      Electrochemistry, 84(7) 524–528 (2016).
2.内本 喜晴, 折笠 有基, 「X線吸収分光法によるリチウムイオン二次電池電極・電 解質界面におけるin situ測定」, Electrochemistry, 80(9) 648–653 (2012).

著書

1.折笠 有基, 内本 喜晴(分担), 「PEFCの内部現象・反応機構と評価・解析技   術」, 第2章2 「XAFS解析によるコアシェル触媒の電子・局所構造解析と活性支配因 子および劣化機構の解明」, S&T出版, 2015.
2.折笠 有基, 内本 喜晴(分担), 「太陽電池におけるエネルギー貯蔵」, 第4章1   「蓄電池」, シーエムシー出版, 2014.
3.折笠 有基, 内本 喜晴(分担), 「XAFS/EELSによる局所構造解析・状態分析技  術」, 第4章1 「XAFSによるリチウムイオン二次電池の電極・電解質界面の解析」,  情報機構, 2014.
4.折笠 有基, 王 小明(分担),「燃料電池-2015年のFCV一般販売開始を前にした技 術動向と課題」, 「XAFS解析」, 工業材料, 2014.
5.折笠 有基, 荒井 創(分担),「SPring-8の高輝度放射光を利用したグリーンエネ ルギー分野における電池材料開発」, 第2章3 「放射光その場時間分解測定を用いた リチウムイオン電池正極の相変化機構解明」, シーエムシー出版, 2014.
6.折笠 有基, 内本 喜晴(分担), 「SPring-8の高輝度放射光を利用したグリーンエ ネルギー分野における電池材料開発」, 第2章4 「二次元イメージングX線吸収分光法 を用いたリチウムイオン電池合剤電極の反応分布解析」, シーエムシー出版, 2014.
7.折笠 有基, 内本 喜晴(分担), 「リチウムイオン2次電池の革新技術と次世代2次 電池の最新技術」, 第9章 「放射光によるリチウムイオン電池の計測」, 技術教育出 版社, 2013.
8.Y. Orikasa, T. Masese, Y. Uchimoto, “Nanoscale Technology for Advanced  Lithium Batteries”, Chapter 10, “Characterization of Neighbor Atoms”    Springer, 2013.
9.内本 喜晴, 折笠 有基, 奥村 豊旗(分担), 「全固体電池の最前線」, 第19章,   「放射光を用いた全固体リチウム二次電池電極/電解質の界面評価」, シーエムシー 出 版, 2011.

招待講演

1.折笠 有基, “リチウムイオン電池における反応不均一現象と性能の相関性”, 日本化 学会電気化学ディビジョン 化学電池材料研究会 第38回講演会, 2016/9/4, 奈良.
2.Y. Orikasa, M. Hattori, T. Mori, K. Yamamoto, K. Nakanishi, Y. Uchimoto,   “Magnesium Rechargeable Battery using Polyanion Compound Cathode   and Ether-Based Electrolyte”, 1st International Symposium on Magnesium  Batteries, 2016/7/21, Ulm, Germany.
3.折笠 有基, “放射光を用いた蓄電池研究の最前線”, 立命館大学SRセンター研究成果 報告会, 2016/6/11, 滋賀.
4.Y. Orikasa, T. Yoshinari, E. Kato, T. Mori, K. Nakanishi, Y. Uchimoto,     “Mechanism of Enhanced Rate Capability by Interfacial Modification     between LiFePO4 Cathode and Electrolyte”, 2016 MRS Spring Meeting,    2016/3/29, Arizona, USA.
5.折笠 有基, “放射光オペランド測定による電気化学デバイスの時間・空間的階層反 応解析と高性能化”, 平成27年度第1回関西電気化学研究会, 2015, 大阪.
6.折笠 有基, 内本 喜晴, “薄膜モデル電極を用いた電極/電解質界面の構造設計と 高容量マグネシウム二次電池の創製”, 第43回 薄膜・表面物理セミナー, 2015, 東京.
7.折笠 有基, “硬X線回折・吸収分光を用いたリチウムイオン電池のオペランド観測”,  放射光学会第7回若手研究会, 2014, 千葉.
8.折笠 有基, “ポリアニオン化合物正極を用いた高容量マグネシウム二次電池の開発 と課題”, アドバンスト・バッテリー技術研究会 第145 回定例研究会, 2014, 京都.
9.折笠 有基, 内本 喜晴, “放射光X線を駆使した電気化学エネルギー変換デバイスの 反応機構解明”, 第1回アラインス若手研究交流会, 2013, 仙台.
10.Y. Orikasa, T. Masese, K. Yamamoto, Z, Huang, T. Mori, M. Hattori, T. Abe,  C. Tassel, Y. Kobayashi, H. Kageyama, J. Kim, T. Minato, Y. Uchimoto,    “Magnesium Secondary Battery Using Polyanion Compound Cathode     Materials”, The 7th Asian Electrochemical Power Sources, 2013, Osaka.
11.折笠 有基, “リチウムイオン電池の反応における階層構造と放射光X線解析”, 立命 館大学SRセンター研究成果報告会, 2013, 滋賀.
12.Y. Orikasa, T. Okado, T. Kamiji, Y. Uchimoto, “Reaction Mechanism of    MnO2 Nanosheets as Cathode Materials for Magnesium Secondary      Battery”, Renewable Energy and Materials